研究院致力打造科学研究及人才培养高地
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姓名: 张淳
职称: 教授 博士生导师
邮箱:chunzhang@tju.edu.cn
研究方向: 有机化学 有机合成方法学研究 化学反应机理研究 光电材料研究.
个人简介
2008年毕业于中国药科大学基础药学理科基地班,获学士学位。2013年毕业于北京大学药学院,获博士学位。2014年——2017年在美国犹他大学从事博士后研究。2017年在天津大学参加工作。
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课题组主页:https://www.x-mol.com/groups/chunzhang
研究成果
1. Chun Zhang, Brandon Tutkowski, Ryan J. DeLuca, Leo A. Joyce, Olaf Wiest, Matthew S. Sigman*, Palladium-catalyzed enantioselective Heck alkenylation of trisubstituted allylic alkenols: a redox-relay strategy to construct vicinal stereocenters, Chem. Sci. 2017, 8, 2277.
2.Chun Zhang, Celine B. Santiago, Jennifer M. Crawford, Matthew S. Sigman*, Enantioselective Dehydrogenative Heck Arylations of Tri-substituted Alkenes with Indoles to Construct Quaternary Stereocenters, J. Am. Chem. Soc. 2015, 137, 15668.
3.Chun Zhang, Celine B. Santiago, Lei Kou, Matthew S. Sigman*, Alkenyl Carbonyl Derivatives in Enantioselective Redox Relay Heck Reactions: Accessing α,β-Unsaturated Systems, J. Am. Chem. Soc. 2015, 137, 7290.
4. Chun Zhang, Ning Jiao*, A Cu-catalyzed Practical Approach to α-Ketoesters under Air: an Efficient Aerobic Oxidative Dehydrogenative Coupling of Alcohols and α-Carbonyl Aldehydes, Org. Chem. Frontiers, 2014, 1, 109.
5. Chun Zhang, Xiaoyang Wang, Ning Jiao*, Copper-Catalyzed Aerobic Oxidative C–C Bond Cleavage of 1,3-Diaryldiketones To Synthesize 1,2-Diketones, Synlett, 2014, 25, 1458.
6. Chun Zhang, Peng feng, Ning Jiao*, Cu-Catalyzed Esterification Reaction via Aerobic Oxygenation and C–C Bond Cleavage: An Approach to α-Ketoesters, J. Am. Chem. Soc. 2013, 135, 15257.
7. Chun Zhang, Liangren Zhang, Ning Jiao*, Catalyst and additive free procedure to construct benzimidazoles using air as the oxidant under room temperature. Green Chem. 2012, 14, 3273.
8. Chun Zhang, Conghui Tang, Ning Jiao*, Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process, Chem. Soc. Rev. 2012, 41, 3464.
9. Zejun Xu,§ Chun Zhang,§ Ning Jiao*, (§ These authors contributed equally to this work) Copper-mediated aerobic oxidative dehydrogenative annulation of aldehydes, amines and molecular oxygen for oxazoles via C-H functionalization and dioxygen activation. Angew. Chem. Int. Ed. 2012, 51, 11367.
10. Chun Zhang, Xiaolin Zong, Liangren Zhang, Ning Jiao*, Copper-catalyzed aerobic oxidative cross-dehydrogenative coupling (CDC) of amine and α-carbonyl aldehyde: a pratical and efficient method to α-ketoamides with wide substrate scope. Org. Lett. 2012, 14, 3280.
11. Chun Zhang, Zejun Xu, Tao Shen, Guolin Wu, Liangren Zhang, Ning Jiao*, Mn-mediated aerobic oxidative C-C bond cleavage of aldehydes with dioxygen activation: a simple synthetic approach to formamide. Org. Lett. 2012, 14, 2362.
12. Chun Zhang, Zejun Xu, Liangren Zhang, Ning Jiao*, Et3N-catalyzed dehydrogenative oxidation of α-unsubstituted carbonyl compounds with aryl diamine leading to quinoxalines using molecular oxygen as oxidant. Tetrahedron. 2012, 68, 5258.
13. Chun Zhang, Liangren Zhang, Ning Jiao*, Multiple oxidative dehydrogenative functionalization of aryl acetaldehydes using molecular oxygen as oxidant leading to 2-oxo-acetamidines. Adv. Synth. Catal. 2012, 354, 1293.
14. Chun Zhang, Zejun Xu, Liangren Zhang, Ning Jiao*, Copper-catalyzed aerobic oxidative coupling of aryl acetaldehydes with anilines leading to α-ketoamides, Angew. Chem. Int. Ed. 2011, 50, 11088.
15. Chun Zhang, Ning Jiao*, Copper-catalyzed aerobic oxidative dehydrogenative coupling of anilines leading to aromatic azo compounds using dioxygen as an oxidant, Angew. Chem. Int. Ed. 2010, 49, 6174.
16. Chun Zhang, Ning Jiao*, Dioxygen activation under ambient conditions: Cu-catalyzed oxidative amidation−diketonization of terminal alkynes leading to α-ketoamides, J. Am. Chem. Soc. 2010, 132, 28.
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